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Mesoporous Fe2O3 nanoparticles as high performance anode materials for lithium-ion batteries
Affiliation:1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, Shanghai 200438, China;2. Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), 3 Research Link, Singapore 117602, Singapore
Abstract:This work introduces an effective, inexpensive, and large-scale production approach to the synthesis of Fe2O3 nanoparticles with a favorable configuration that 5 nm iron oxide domains in diameter assembled into a mesoporous network. The phase structure, morphology, and pore nature were characterized systematically. When used as anode materials for lithium-ion batteries, the mesoporous Fe2O3 nanoparticles exhibit excellent cycling performance (1009 mA h g 1 at 100 mA g 1 up to 230 cycles) and rate capability (reversible charging capacity of 420 mA h g 1 at 1000 mA g 1 during 230 cycles). This research suggests that the mesoporous Fe2O3 nanoparticles could be suitable as a high rate performance anode material for lithium-ion batteries.
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