Template Synthesis of Polyaniline in the Presence of Poly-(2-acrylamido-2-methyl-1-propanesulfonic Acid) |
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Authors: | Ivanov V F Gribkova O L Cheberyako K V Nekrasov A A Tverskoi V A Vannikov A V |
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Institution: | (1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia;(2) Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia |
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Abstract: | A template oxidative polymerization of aniline in aqueous solutions containing poly-(2-acrylamido-2-methyl-1-propanesulfonic acid) and ammonium persulfate yields a polyaniline complex with the polyacid soluble in water. According to the data of spectral measurements, the process of polymerization is of a pronounced autocatalytic nature. The consequences of this are both the formation of a nonuniform distribution of oxidized and nonoxidized fragments of the polymer chain and the formation of a macroscopic scale of redox nonuniformities in the reaction volume during the process of polymerization. The spectra of absorption of the polyaniline/polyacid films on transparent glass electrodes with a conductive layer of SnO2 and the data of potentiodynamic measurements in the potential region 0–1.0 V (Ag/AgCl) are typical for polyaniline with moderate electroconduction. |
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Keywords: | polyaniline template synthesis polymer complex autocatalysis redox heterogeneity self-organization |
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