Sorption and desorption characteristics of Eu(III) on red earth |
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Authors: | W M Dong X K Wang J Z Du X Y Bian F Ma Z Y Tao |
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Institution: | (1) Radiochemistry Laboratory, College of Chemistry and Chemical Engineering, Lanzhou University, 730000 Lanzhou, P.R. China |
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Abstract: | The batch method and the column method were simultaneously employed to study the sorption and desorption of Eu(III) on red
earth as a function of pH (4.6–6), the presence of a well-characterized fulvic acid (FA) and the iron oxides content of red
earth. The results from both methods were consistent qualitatively. The Eu(III) sorption showed significant dependences on
pH and FA, the sorption was increased with increasing pH and by addition of FA to the solutions, while the iron oxides content
of the red earth had a negative contribution to the sorption of Eu(III). Additionally, the sorption-desorption hysteresis
of Eu(III) on red earth occurred at a pH range of 4.6–6. Therefore, the humic substance and high pH have a great tendency
to immobilize Eu(III) on red earth. |
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