Preparation of iron carbonyl complexes of germanium(II) and tin(II) each with a terminal fluorine atom |
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| Authors: | Anukul Jana Herbert W. Roesky Carola Schulzke |
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| Affiliation: | a Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany
b School of Chemistry, Trinity College Dublin, Dublin 2, Ireland |
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| Abstract: | The reaction of β-diketiminate substituted germanium(II) and tin(II) fluorides (LGeF (1) and LSnF (2)) (L = CH{(CMe)2(2,6-iPr2C6H3N)2}) with diiron nonacarbonyl, Fe2(CO)9 at room temperature, leads to the iron carbonyl complexes of germanium(II) LGeFFe(CO)4 (3) and tin(II) LSnFFe(CO)4 (4), respectively. Compounds 3 and 4 were characterized by elemental analysis, NMR spectroscopy, and mass spectrometry. Furthermore, both complexes (3 and 4) were investigated by X-ray structural analysis which shows that both compounds are monomeric in the solid state containing terminal fluorine atoms. |
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| Keywords: | Germanium(II) Tin(II) Fluoride Iron carbonyl |
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