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CF3 radicals from triflic anhydride and collidine: Their trapping by a trimethylsilylenolether
Authors:Henri Rudler,André  e Parlier,Charline Denneval,Patrick Herson
Affiliation:Institut Parisien de Chimie Moléculaire UMR CNRS 7201, Université Pierre et Marie Curie, CC 47, 4 place jussieu 75252 Paris cedex 5, France
Abstract:The interaction of triflic anhydride with s-collidine in the presence of the (trimethylsilyl)enolether of acetophenone led to duplication products the structure of which could only be explained by the formation of CF3 radicals.
Keywords:Triflic anhydride   Collidine   CF3 radicals   (Trimethylsilyl)enolether   Dimerization
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