Synthesis of 5-(perfluoroalkylmethyl)-1,3-dioxolan-4-ones |
| |
Authors: | Ikram Chehidi Abaccar Ould Amanetoullah Ahmed Baklouti |
| |
Affiliation: | a Faculty of Sciences of Tunis, Department of Chemistry, Laboratory of Structural Organic Chemistry, Campus Universitaire, 2092 El Manar, Tunis, Tunisia b Ecole Supérieure des Industries Alimentaires, 58, Avenue Alain Savary, 1003 Tunis, Tunisia |
| |
Abstract: | Acid catalysed condensation of F-alkyl α-hydroxy acids with simple aldehydes or ketones gave F-alkyl 1,3-dioxolan-4-ones. When BF3,OEt2 was used as the catalyst, the condensation products were obtained in moderate to good yields and the “cis” isomers are largely favoured, while with HOTs/H2SO4 as catalyst, poor yields and lower stereoselectivities were observed. |
| |
Keywords: | F-Alkyl α-Hydroxy acid 1,3-Dioxolan-4-one Condensation |
本文献已被 ScienceDirect 等数据库收录! |
|