Synthesis, structural, spectroscopic and reactivity properties of a new N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine ligand and its Cu(II) and Pd(II) complexes |
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Authors: | Veli T Kasumov Ibrahim Uçar |
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Institution: | a Department of Chemistry, Harran University, Osmanbey, 63300 ?anl?urfa, Turkey b Department of Physics, Faculty of Arts and Sciences, Ondokuz May?s University, 55139 Kurupelit, Samsun, Turkey |
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Abstract: | A new N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine (1) complexes with Cu(II) (2) and Pd(II) (3) have been synthesized and characterized by X-ray crystallography, UV-Vis, IR, 1H NMR and EPR spectroscopic techniques. The X-ray crystal structure of complex 2 reveals tetrahedrally distorted square-planar coordination geometry around Cu(II). The UV/Vis and EPR results indicate that the solid state geometry of 2 remains unchanged in solutions. Chemical oxidation of 3 with Ce(IV) in CHCl3 generates relatively stable Pd(II)-phenoxyl radical complex (g = 2.0073). The results related with the chemical oxidation of 2 and 3 as well as the catalytic activity of 3 in the hydrogenation of PhNO2 are presented. |
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Keywords: | Trifluorinated-3 5-di-tert-butylsalicylaldimine Cu(II) and Pd(II) complexes X-ray structure Spectroscopy Chemical oxidation |
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