2-Fluoro-3-phenyl-allyltrimethylsilane: A new fluorinated reagent for Hosomi-Sakurai reaction |
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| Authors: | Tsuyoshi Hayashi Hideo Iio |
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| Institution: | Department of Material Science, Osaka City University, Sugimoto, Sumiyoshi, Osaka 558-8585, Japan |
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| Abstract: | 2-Fluoro-3-phenyl-allyltrimethylsilane, prepared from β-fluorinated allylic acetate via a π-allylpalladium intermediate, reacted with various aldehydes and acetals in the presence of TiCl4 to afford the corresponding homoallyl alcohols and homoallyl ethers, respectively, in good to moderate yields. |
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| Keywords: | Hosomi-Sakurai reaction β-Fluorinated allylsilane Lewis acid-promoted allylation |
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