Asymmetric [3 + 2] annulations catalyzed by a planar-chiral derivative of DMAP |
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Authors: | Bappert Erhard Müller Peter Fu Gregory C |
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Institution: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA. |
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Abstract: | A planar-chiral DMAP derivative catalyzes an intriguing 3 + 2] annulation reaction of silylated indenes to produce diquinanes that bear three contiguous stereocenters (one quaternary and two tertiary). |
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