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Asymmetric [3 + 2] annulations catalyzed by a planar-chiral derivative of DMAP
Authors:Bappert Erhard  Müller Peter  Fu Gregory C
Institution:Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Abstract:A planar-chiral DMAP derivative catalyzes an intriguing 3 + 2] annulation reaction of silylated indenes to produce diquinanes that bear three contiguous stereocenters (one quaternary and two tertiary).
Keywords:
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