Radiation-induced nitration of organic compounds in aqueous solutions |
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Authors: | B G Ershov A V Gordeev G L Bykov |
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Institution: | (1) Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninskii prospekt, Moscow, 119991, Russia |
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Abstract: | Radiation-induced nitration of organic compounds in aqueous solutions was studied. It was found that γ-irradiation of solutions
containing acetic and nitric acid and/or their salts gives nitromethane. Dependences of the product yield on the absorbed
dose and the contents of components were established. The mechanism of radiation nitration involving radicals is discussed. |
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