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Radiation-induced nitration of organic compounds in aqueous solutions
Authors:B G Ershov  A V Gordeev  G L Bykov
Institution:(1) Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninskii prospekt, Moscow, 119991, Russia
Abstract:Radiation-induced nitration of organic compounds in aqueous solutions was studied. It was found that γ-irradiation of solutions containing acetic and nitric acid and/or their salts gives nitromethane. Dependences of the product yield on the absorbed dose and the contents of components were established. The mechanism of radiation nitration involving radicals is discussed.
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