Ferromagnetic NiII-GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands |
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| Authors: | Yamaguchi Tomoka Sunatsuki Yukinari Kojima Masaaki Akashi Haruo Tsuchimoto Masanobu Re Nazzareno Osa Shutaro Matsumoto Naohide |
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| Affiliation: | Department of Chemistry, Faculty of Science, Okayama University, Tsushima-naka 3-1-1, Okayama 700-8530, Japan. |
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| Abstract: | Dinuclear [(NiL)Gd(hfac)(2)(EtOH)](H(3)L = 1,1,1-tris(N-salicylideneaminomethyl)ethane, Hhfac = hexafluoroacetylacetone), trinuclear [(NiL)(2)Gd(NO(3))], and tetranuclear [(NiL)Gd(CH(3)CO(2))(2)(MeOH)](2) complexes, were prepared by treating [Ni(HL)] with [Gd(hfac)(3)(H(2)O)(2)], Gd(NO(3))(3).6H(2)O, and Gd(CH(3)CO(2))(3).4H(2)O, respectively, in the presence of Et(3)N. All the complexes show that ferromagnetic interactions occur between the Ni(II) and Gd(III) ions. |
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