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Structure and dynamics of oxide melts and glasses: A view from multinuclear and high temperature NMR
Authors:Dominique Massiot  Franck Fayon  Valérie Montouillout  Nadia Pellerin  Julien Hiet  Claire Roiland  Pierre Florian  Jean-Pierre Coutures  Laurent Cormier  Daniel R Neuville
Institution:1. Centre de Recherches sur les Matériaux à Haute Température, CRMHT-CNRS, UPR4212 and Université d’Orléans, 1D avenue de la Recherche Scientifique, 45071 Orléans Cedex 2, France;2. PROMES-CNRS, Perpignan, France;3. IMPMC, CNRS UMR 7590, Université Paris 6, Université Paris 7, 140 rue de Lourmel, 75015 Paris, France;4. Physique des Minéraux et Magmas, CNRS-UMR 7154 IPGP, Paris, France
Abstract:From a presentation of the various nuclear magnetic resonance (NMR) experiments that allows to characterize the local structure and dynamics of oxide glasses and melts, we show that it becomes possible to evidence not only the details of the coordination state of the constituting atoms but also the nature of polyatomic molecular motifs extending over several chemical bonds.
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