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Crystal structure and optical spectra of LiLa9(SiO4)6O2 crystals activated with Er3+
Authors:Marco Bettinelli  Adolfo Speghini  Daniele Falcomer  Enrico Cavalli  Gianluca Calestani  Marta Quintanilla  Eugenio Cantelar  Fernando Cussó
Affiliation:1. Dipartimento Scientifico e Tecnologico, University of Verona and INSTM, UdR Verona, Ca’ Vignal, Strada Le Grazie 15, 37134 Verona, Italy;2. Dipartimento di Scienze, Tecnologie e Mercati della Vite e de Vino, University of Verona and INSTM, Villa Lebrecht, San Floriano, 37029 Verona, Italy;3. Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Università di Parma, Viale G. P. Usberti 17/a, 43100 Parma, Italy;4. Departamento de Física de los Materiales, Facultad de Ciencias, Universidad Autónoma de Madrid, Madrid 28049, Spain;1. Departamento de Física de Materiales, Universidad Autónoma de Madrid, 28049 Madrid, Spain;2. Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas, 28049 Madrid, Spain;3. Departamento de Física de Materiales, Universidad Autónoma de Madrid, 28049 Madrid, Spain
Abstract:LiLa9(SiO4)6O2 (LLS) crystals activated with Er3+ have been grown by the flux growth method. Their apatite structure has been characterized by single-crystal X-ray diffraction. The absorption and emission spectra have been measured in the visible and NIR regions. They are affected by a significant inhomogeneous broadening making these crystals interesting active media for tunable solid-state laser operation.
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