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Carborane-derived diphosphites: New ligands for Pd-catalyzed allylic amination |
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| Authors: | Sergey E. Lyubimov Andrey A. Tyutyunov Pavel A. Vologzhanin Anton S. Safronov Pavel V. Petrovskii Valery N. Kalinin Konstantin N. Gavrilov Vadim A. Davankov |
| Affiliation: | 1. Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, 119991 Moscow, Russia;2. Department of Chemistry, Ryazan State University, 46 Svoboda Street, 390000 Ryazan, Russia |
| Abstract: | A series of chiral diphosphite ligands bearing sterically congested carborane fragments have been prepared and applied in the Pd-catalyzed allylic amination of 1,3-diphenylallyl acetate with pyrrolidine and di-n-propylamine (up to 83% ee). |
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