Phase separation and crystallization in a melt-spun Ti45Zr35Ni17Cu3 alloy |
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Authors: | Limin Wang Baozhong Liu Liqun Ma Chaoli Ma Akihisa Inoue |
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Institution: | 1. Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, CAS, Changchun 130022, China;2. Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan;3. Department of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China |
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Abstract: | Structure and crystallization behavior of amorphous and quasicrystalline Ti45Zr35Ni17Cu3 alloy have been studied. DSC trace of the amorphous alloy obtained during continuous heating to 1300 K shows distinctly an exothermic peak and two endothermic peaks. The amorphous alloy has different structures depending on annealing temperature. The first exothermic reaction at low temperature region from 400 K to 900 K is due to the precipitation of an icosahedral quasicrystalline phase, and the second endothermic reaction at higher temperature region from 950 K to 990 K results from the transformation of the I-phase to C14 Laves and α-(Ti, Zr) phases. |
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