Pyrimidine sigma-complexes. 7. The recyclization of 5-nitropyrimidine and its methoxy derivatives upon reaction with the acetylacetone carbanion |
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| Authors: | G. Ya. Remennikov L. K. Kurilenko I. V. Boldyrev V. M. Cherkasov |
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| Affiliation: | (1) Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, 252660 Kiev |
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| Abstract: | A study was carried out on the reaction of 5-nitro and 5-nitromethoxypyrimidines with the acetylacetone carbanion. Benzene and pyridine derivatives are formed as a result of recyclization. The direction of the reaction depends on the position of the substituents in the pyrimidine ring and the nature of the bases.Communication 6, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 508–512, April, 1987. |
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