Dimerization of dioxovanadium(v) ions in the presence of cyclohexenyl hydroperoxide |
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| Authors: | I S Ionova V L Roubaijlo |
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| Institution: | (1) N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977 Moscow, Russian Federation |
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| Abstract: | The structure and properties of the intermediate that is formed in the reaction of VO(DMSO)5(ClO4)2 with cyclohexenyl hydroperoxide and characterized by the band at λmax=402 nm in the electronic absorption spectra of its solution were considered using quantum-chemical concepts.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1443–1446, August, 1997. |
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| Keywords: | vanadium complexes electronic absorption spectra |
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