Synthesis of the C59N+ carbocation. A monomeric azafullerene isoelectronic to C60 |
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| Authors: | Kim Kee-Chan Hauke Frank Hirsch Andreas Boyd Peter D W Carter Elizabeth Armstrong Robert S Lay Peter A Reed Christopher A |
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| Institution: | Department of Chemistry, University of California, Riverside, California 92521-0403, USA. |
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| Abstract: | A heterofullerene isoelectronic to C60 is reported. The azafullerenium cation C59N+ can be isolated in good yield as a carborane salt via the two-electron oxidation of the C-C bond of (C59N)2 dimer. C59N]Ag(CB11H6Cl6)2] has been characterized by electronic, IR, Raman, and 13C NMR spectroscopies, MALDI spectrometry, DFT calculations, and X-ray crystallography. |
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