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Reaction of 2-thiopyrrolidones with monochloroacetic acid and its methyl ester |
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| Authors: | G. V. Bespalova V. A. Sedavkina E. V. Ponomareva A. D. Shebaldova V. I. Labunskaya |
| Affiliation: | (1) N. G. Chernyshevskii Saratov State University, 410026 Saratov |
| Abstract: | Calculations of the electronic structure of 5-alkyl-2-thiopyrrolidones and their oxygen analogs were carried out by the MO LCAO method in the CNDO/2 approximation. The obtained data were used to discuss the reactivity of the investigated compounds in the alkylation of monochloroacetic acid, leading, in the case of 2-thiopyrrolidones, to the formation of the corresponding thiazolinones.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1690–1692, December, 1986. |
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