Monohalogenobenzoylhydrazones VI. New antimony(III) complexes with monochlorobenzoylhydrazones of 2-furaldehyde, 2-pyrrolaldehyde and 2-thiophenaldehyde as ligands |
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Authors: | Tossidis I A Bolos C A Christofides A |
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Institution: | (1) Department of General and Inorganic Chemistry, Aristotelian University of Thessaloniki, P.O.B. 135, 54006, Greece |
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Abstract: | The antimony(III) trihalides, SbX3 (X=Cl, Br and I), react with the title ligands to give the compounds SbX3L, where L=benzoyl- and monochlorobenzoylhydrazones of 2-furaldehyde (FBHH and FClBHH), 2-pyrrolaldehyde (PBHH and PClBHH) and 2-thiophenaldehyde (TBHH and TClBHH). The characterization of the new species was based on their elemental analyses, spectral data (IR and UV-Vis) and thermal studies. The ligands appear to offer two coordination sites (the carbonyl and azomethine groups) and perhaps a third one (the heteroatom of the heterocyclic ring). The thermal decompositions of the studied complexes proceed via one or three stages, the number of stages depending on the nature of both the hydrazones and the halogens. The structures proposed for the investigated complexes are either pseudo- or distorted octahedral.
Zusammenfassung Antimon(III)-trihalogenide, SbX3 (X=Cl, Br und I) reagieren mit den Titelliganden und liefern Verbindungen der allgemeinen Formel SbX3L (L=Benzoylbzw. Monochlorobenzoylhydrazon von 2-Furfuraldehyd (FBHH und FClBHH), von 2-Pyrrolaldehyd (PBHH und PClBHH) und von 2-Thiophenaldehyd (TBHH und TClBHH). Die neuen Verbindungen wurden mittels Elementaranalyse, Spektraldaten (IR und UV) sowie thermischen Untersuchungen beschrieben. Zwei Koordinationsstellen scheinen von den Liganden bevorzugt zu sein: die Carbonylund die Azomethingruppe. Eine dritte könnte das Heteroatom des heterocyclischen Ringes sein. Die thermische Zersetzung der untersuchten Komplexe vollzieht sich in Abhängigkeit von der Natur der Hydrazone und der Halogene in einem oder in drei Schritten. Als Struktur für die untersuchten Komplexe wird eine pseudo-oder verzerrte oktaedrische Struktur vorgeschlagen.
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![chcy](/content/v212w1g585518616/xxlarge1095.gif) ![iecy](/content/v212w1g585518616/xxlarge1077.gif) ![scy](/content/v212w1g585518616/xxlarge1089.gif) ![kcy](/content/v212w1g585518616/xxlarge1082.gif) ![acy](/content/v212w1g585518616/xxlarge1072.gif) .
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