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Kinetic study of isopropanol dehydration over silicoaluminophosphate catalyst
Authors:A. S. Araujo   M. J. B. Souza   V. J. Fernandes Jr.  J. C. Diniz
Affiliation:(1) Department of Chemistry, Federal University of Rio Grande do Norte, CP 1662, 59078-970 Natal, RN, Brazil
Abstract:The catalytic dehydration of isopropanol has been studied over a solid acid silicoaluminophosphate type SAPO-5. The reaction was processed varying the temperature and weight hourly space velocity, using a fixed bed continous flow reactor. The isopropanol undergoes inter- and intramolecular dehydration, forming propylene and isopropyl ether, respectively. Nevertheless, the catalyst was selective to the olefin, with an activation energy of the order of 46.1 kJ/mol.
Keywords:Silicoaluminophosphate  alcohol dehydration  kinetic study
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