Sovolthermal Synthesis and Crystal Structure of Two CdII Coordination Polymers of Benzenedicarboxylic |
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| Authors: | Fang Zhang Feng-Li Bei Jie-Ming Cao |
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| Institution: | (1) Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing, 210094, P.R. China;(2) College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, P.R. China |
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| Abstract: | Abstract Two cadmium coordination polymers of benzenedicarboxylic: C8H6CdO5]n (1) and C8H10CdO7]n·4H2O (2), have been synthesized by sovolthermal method and characterized by single-crystal X-ray diffraction. Our experimental results
suggest that complex 1 crystallizes in orthorhombic space group Pbcm with a = 6.4978(8) ?, b = 6.9475(9) ?, c = 18.319(2)
?, and Z = 4. Structural analysis reveals that complex 1 features a three-dimensional framework structure formed by strong
coordination bond and weak hydrogen bond force. Complex 2 crystallizes in orthorhombic space group Pcca with a = 7.293(2),
b = 9.980(3), c = 19.889(6), and Z = 4. Complex 2 exhibits a layered framework structure formed by extensive inter-chain hydrogen
bond interaction.
Index Abstract Two cadmium coordination polymers of benzenedicarboxylic: C8H6CdO5]n (1) and C8H10CdO7]n·4H2O (2), have been synthesized by sovolthermal method and characterized by single-crystal X-ray diffraction
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| Keywords: | Sovolthermal Coordination polymer p-BDC m-BDC |
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