Mechanism of electrochemical oxidation of 1-chloro-2,2,6,6-tetramethylpiperidine |
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| Authors: | Kagan E. Sh. Yanilkin V. V. Morozov V. I. Nastapova N. V. Zhukova I. Yu. Kashparov I. I. Kashparova V. P. |
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| Affiliation: | (1) South-Russian State Technical University (Novocherkassk Polytechnical Institute), ul. Prosveshcheniya 132, Novocherkassk, 346421, Russia;(2) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia |
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| Abstract: | In contrast to 2,2,6,6-tetramethylpiperidine and other aliphatic amines, at the electrochemical oxidation of 1-chloro-2,2,6,6-tetramethylpiperidine a sufficiently stable cation-radical is formed. Its formation is confirmed by the data of cyclic voltammetry and electron paramagnetic resonance. Further transformation of the cation-radical leads to the formation of 2,2,6,6-tetramethylpiperidin-1-oxyl. |
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