Peculiarities of the thermal polymerization of the complex-bonded acrylamide |
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Authors: | D. A. Kritskaya V. S. Savost'yanov A. N. Ponomaryev |
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Affiliation: | (1) Branch of the Institute of Energetic Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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Abstract: | Peculiarities of the thermal polymerization of acrylamide bonded in a complex with CoII, NiII, or CuII nitrate have been studied by differential scanning calorimetry. The polymerization can occur in the regions prior to the melting of the complex, during melting, or right after it, depending on the rate of heating and the nature of the complexing agent. The effect of the addition of water and inorganic or polymeric powders on the form and character of the polymerization thermograms, which have a complex multimodal structure in the polymerization region, has been studied. The analysis of the results obtained indicates that during heating and melting complexes of a number of structures differing in their polymerization properties are formed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1410–1413, August, 1993. |
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Keywords: | acrylamide, complexes polymerization differential scanning calorimetry |
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