| Diastereoselective Michael Addition of (4''''S)-Ethyl-3-(2'''',2''''-Dimethyl-1'''',3''''- dioxolan-4''''-yl) acrylate with Furyl Lithium |
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| 引用本文： | Dong Mei HAN,Xun Tian JIANG,Jian Hong CHEN,Bin WANG,Dong Lu BAI* Shanghai Institute of Meteria Medica,Shanghai Institutes for Biological Sciences,Chinese Academy of Sciences,Shanghai 200031. Diastereoselective Michael Addition of (4''''S)-Ethyl-3-(2'''',2''''-Dimethyl-1'''',3''''- dioxolan-4''''-yl) acrylate with Furyl Lithium[J]. 中国化学快报, 2001, 0(5) |
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| 作者姓名： | Dong Mei HAN Xun Tian JIANG Jian Hong CHEN Bin WANG Dong Lu BAI* Shanghai Institute of Meteria Medica Shanghai Institutes for Biological Sciences Chinese Academy of Sciences Shanghai 200031 |
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| 作者单位： | Dong Mei HAN，Xun Tian JIANG，Jian Hong CHEN，Bin WANG，Dong Lu BAI* Shanghai Institute of Meteria Medica，Shanghai Institutes for Biological Sciences，Chinese Academy of Sciences，Shanghai 200031 |
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| 摘 要： | Recently we reported that the diastereoselective intramolecular [4+3] cycloaddition of 4 led to the formation of cycloadduct 5 as the only isolated isomer in 50% yield. The chiral C-3 of compound 4 could be used to direct the stereochemical course of [4+3] cycloaddition enabling the control of the relative stereochemistry between three contiguous asymmetric centers in adduct 51. The stereogenic center at C-3 of 4 was constructed by the asymmetric Michael addition of (, (-unsaturated ester 2 w…
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Diastereoselective Michael Addition of (4''''S)-Ethyl-3-(2'''',2''''-Dimethyl-1'''',3''''- dioxolan-4''''-yl) acrylate with Furyl Lithium |
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| Dong Mei HAN,Xun Tian JIANG,Jian Hong CHEN,Bin WANG,Dong Lu BAI. Diastereoselective Michael Addition of (4''''S)-Ethyl-3-(2'''',2''''-Dimethyl-1'''',3''''- dioxolan-4''''-yl) acrylate with Furyl Lithium[J]. Chinese Chemical Letters, 2001, 0(5) |
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| Authors: | Dong Mei HAN Xun Tian JIANG Jian Hong CHEN Bin WANG Dong Lu BAI |
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| Affiliation: | Dong Mei HAN,Xun Tian JIANG,Jian Hong CHEN,Bin WANG,Dong Lu BAI* Shanghai Institute of Meteria Medica,Shanghai Institutes for Biological Sciences,Chinese Academy of Sciences,Shanghai 200031 |
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| Abstract: | |
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| Keywords: | Michael addition configuration determination syn addition. |
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