| 磺化苯膦酸锆催化反应研究 |
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| 引用本文： | 傅相锴 罗必奎. 磺化苯膦酸锆催化反应研究[J]. 应用化学, 1991, 8(5): 6-9 |
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| 作者姓名： | 傅相锴 罗必奎 |
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| 作者单位： | 西南师范大学化学系，西南师范大学化学系，西南师范大学化学系 重庆 630715，重庆 630715，重庆 630715 |
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| 摘 要： | 本文首次对碘化苯膦酸锆催化酯化、缩醛、缩酮、醚化、醇脱水成烯等典型有机反应进行了较系统的研究。反应收率均在90％以上。使用该催化剂,操作方便,后处理简单,无废酸液排放,催化剂可重复使用和再生,是一种很有发展前途的新型固体酸催化剂。
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| 关 键 词： | 磺化苯膦酸锡 固体酸催化剂 酯化 醚化 醇脱水成烯 |
| 收稿时间： | 1990-06-18 |
SOME REACTIONS CATALYZED BY ZIRCONIUM SULPHOPHENYLPHOSPHONATE |
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| Fu Xiangkai,Luo Bikui,Lei Qingying. SOME REACTIONS CATALYZED BY ZIRCONIUM SULPHOPHENYLPHOSPHONATE[J]. Chinese Journal of Applied Chemistry, 1991, 8(5): 6-9 |
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| Authors: | Fu Xiangkai Luo Bikui Lei Qingying |
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| Affiliation: | Fu Xiangkai,Luo Bikui,Lei Qingying Department of Chemistry,Southwest-China Teacher's University,Chongqing,Sichuan 630715 |
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| Abstract: | Some organic reactions such as esterification, acetal and ketal formation, etheration andpreparation of alklene by alcohol dehydration have been first studied using zirconium sul-phophenylphosphonate(ZSPP) as catalyst. ZSPP is simple in operation, easy to work up, andhas no waste acidic liquor to drain off during reactions. The catalyst can be reused andregenerated, it is a promising solid acid catalyst |
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| Keywords: | zirconium sulphophenylphosphenate solid acidcatalyst esterification etheration alklene alcohol dehydration |
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