| 四（2,4—二叔戊基苯氧基）酞菁铜（Ⅱ）的合成及其LB膜 |
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| 引用本文： | 李亚君 蔡小平. 四（2,4—二叔戊基苯氧基）酞菁铜（Ⅱ）的合成及其LB膜[J]. 应用化学, 1991, 8(2): 52-55 |
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| 作者姓名： | 李亚君 蔡小平 |
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| 作者单位： | 中国科学院长春物理研究所，中国科学院长春物理研究所，中国科学院长春物理研究所，中国科学院长春物理研究所，中国科学院长春物理研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院长春应用化学研究所 长春 130022，长春 130022，长春 130022 |
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| 摘 要： | 合成了标题酞菁铜衍生物,并通过元素分析,高压液相色谱,紫外光谱,红外光谱,核磁共振谱,电镜,顺磁共振谱及质谱加以确认。该化合物在稀氯仿溶液和LB膜中各以单,双分子缔合的形式存在。Z型沉积形成的单层LB膜对氨气有很高的灵敏度和选择性。
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| 关 键 词： | 酞菁铜衍生物 LB膜 气敏特性 合成 |
| 收稿时间： | 1989-10-27 |
TETRAKIS-4-(2,4-DI-t-PENTYL PHENOXY)PHTHALOCYANINE COPPER(Ⅱ):SYNTHESIS AND LB FILMS THEREFROM |
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| Li Yajun,Pang Xiao min,Jiang Dapeng,Lu Ande,Hua Yulin,Cai Xiaoping,Lin Lin,Chen Wenqi Changchun Institute of Physics,Academia Sinica,Changchun Changchun Institute of Applied Chemistry,Acedemia Sinica,Changchun. TETRAKIS-4-(2,4-DI-t-PENTYL PHENOXY)PHTHALOCYANINE COPPER(Ⅱ):SYNTHESIS AND LB FILMS THEREFROM[J]. Chinese Journal of Applied Chemistry, 1991, 8(2): 52-55 |
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| Authors: | Li Yajun Pang Xiao min Jiang Dapeng Lu Ande Hua Yulin Cai Xiaoping Lin Lin Chen Wenqi Changchun Institute of Physics Academia Sinica Changchun Changchun Institute of Applied Chemistry Acedemia Sinica Changchun |
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| Affiliation: | Li Yajun,Pang Xiao min,Jiang Dapeng,Lu Ande,Hua Yulin,Cai Xiaoping,Lin Lin,Chen Wenqi Changchun Institute of Physics,Academia Sinica,Changchun Changchun Institute of Applied Chemistry,Acedemia Sinica,Changchun 130022 |
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| Abstract: | The title phthalocyanine derivative is easily soluble in chloroform. Electron spectro-scopy showed that the molecules in dilute chloroform solution and LB film therefromobtained were in monomolecular and associated state respectively. The monolayers of the title compound spread from the chloroform solution were depo-sited on solid supports by LB technique according to the Z-type. The surface pressure ofthe film was near 25mN.m~(-1). The chemiresistors prepared from 30-layer LB films of thetitle compound were sensitive to NH_3 gas at concentration of 2ppm with good selectivity. |
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| Keywords: | phthaloeyanine derivative NH_3 sensibility LB film synthesis |
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