| 水溶液电化学法制得的聚噻吩的表征 |
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| 引用本文： | 董绍俊 张文斌. 水溶液电化学法制得的聚噻吩的表征[J]. 应用化学, 1991, 8(1): 50-54 |
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| 作者姓名： | 董绍俊 张文斌 |
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| 作者单位： | 中国科学院长春应用化学研究所电分析化学开放实验室，中国科学院长春应用化学研究所电分析化学开放实验室 长春 130022，长春 130022 |
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| 摘 要： | 以剖层X光电子能谱(XPS)及红外光指(FTIR)为主要手段对高氯酸水溶液中电化学聚合的聚噻吩进行表征,表明有羰基及键合氯存在,并讨论了聚合过程。
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| 关 键 词： | 聚噻吩 表征 X光电子能谱 红外光谱 |
| 收稿时间： | 1989-07-28 |
CHARACTERIZATION OF POLYTHIOPHENE ELECTROCHEMICALLY POLYMERIZED IN AQUEOUS MEDIUM |
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| Dong Shaojun,Zhang wenbin Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Changchun. CHARACTERIZATION OF POLYTHIOPHENE ELECTROCHEMICALLY POLYMERIZED IN AQUEOUS MEDIUM[J]. Chinese Journal of Applied Chemistry, 1991, 8(1): 50-54 |
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| Authors: | Dong Shaojun Zhang wenbin Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Changchun |
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| Affiliation: | Dong Shaojun,Zhang wenbin Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Changchun 130022 |
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| Abstract: | Conducting polythiophene films electrochemically polymerized in aqueous perchloric solu-tion have been characterized by means of reflecting FT-IR spectra, UV-Vis spectra andXPS spectra. The XPS spectra with etching technique were used to obtain the informationin depth. Water seems to participate in the polymerization process of thiopheene and intro-duce oxygen atom into the PTh structure as carbonyl group. ClO_4~- content varied withthe depth of the film. No ClO_4~- was found in the bulk, but at the surface it gave a concen-tration of 8-10mol%, lower than the concentration of PTh in organic solvents. C-Clbonds were formed during the oligomerization of thiophene in concentrated HClO_4 solutionand uniformlly distributed in the PTh film. The conductivity of PTh film is about1S/cm |
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| Keywords: | polythiophene characterization XPS FTIR |
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