| 从磷硅试剂合成烃基膦酯类化合物 |
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| 引用本文： | 赵永镇,李中华.从磷硅试剂合成烃基膦酯类化合物[J].应用化学,1991,8(1):33-37. |
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| 作者姓名： | 赵永镇 李中华 |
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| 作者单位： | 华中师范大学化学系，华中师范大学化学系 武汉 430070，武汉 430070 |
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| 摘 要： | 本文报导三甲基硅氧基亚磷酸酯(一种活性较高的磷硅试剂)与醛酮反应而获得十四个二乙基三甲硅氧基烃基膦酸酯。产物结构经IR,~1HNMR,~(31)PNMR,MS测试和元素分析表征;对反应机理作了初步讨论。
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| 关 键 词： | 磷硅试剂 三甲基硅氧基亚磷酸酯 二乙基三甲硅氧基烃基膦酸脂 醛 酮 合成 |
| 收稿时间： | 1990-03-26 |
SYNTHESIS OF TRIMETHYLSILOXYALKYLPHOSPHONATES FROM SILICON-PHOSPHORUS REAGENT |
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| Zhao YongZhen,Li Zhonghua.SYNTHESIS OF TRIMETHYLSILOXYALKYLPHOSPHONATES FROM SILICON-PHOSPHORUS REAGENT[J].Chinese Journal of Applied Chemistry,1991,8(1):33-37. |
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| Authors: | Zhao YongZhen Li Zhonghua |
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| Institution: | Zhao YongZhen,Li Zhonghua Department of Chemistry,Central China Normal University,Wuhan 430070 |
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| Abstract: | This paper reports a reaction between trimethylsiloxyphosphite (an active silicon-phosp-horus reagent) with aldehydes or ketones, and fourteen compounds of diethyl trimethylsilo-xyalkylphosphonates have been synthesized. The structures of the products were confirmedby IR,~1HNMR,~(31)PNMR,MS and elemental analysis measurements. The reaction mechanismis discussed. |
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| Keywords: | silicon-phosphorus reagent trimethylsiloxyphosphite diethyl trimethylsilox-yalkylphosphonate aldehyde ketone synthesis |
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