From furans to anilines: toward one-pot two-step amination/diels-alder sequences |
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| Authors: | Medimagh Raouf Marque Sylvain Prim Damien Chatti Saber Zarrouk Hédi |
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| Institution: | Institut Lavoisier de Versailles (ILV) UMR CNRS 8180, Université de Versailles-Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78 035 Versailles, Cedex, France. |
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| Abstract: | Selective metal-free amination and Diels-Alder reactions are described in the furan series, leading to polysubstituted anilines or to stable oxabicyclic adducts in high yield. Interestingly, anilines are conveniently prepared through a novel one-pot, two-step amination/Diels-Alder procedure from commercially available 5-bromo-2-furaldehyde. |
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