Synthesis and Structural Studies of Group 2B Transition Metal Complexes with the Bulky Nitrogen Ligand Bis[<Emphasis Type="Italic">N</Emphasis>-(2,6-diisopropylphenyl) imino]acenaphthene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis and Structural Studies of Group 2B Transition Metal Complexes with the Bulky Nitrogen Ligand Bis[N-(2,6-diisopropylphenyl) imino]acenaphthene

Authors:	Usama?El-Ayaan author-information" > author-information__contact u-icon-before" > mailto:usama@mans.edu.eg" title=" usama@mans.edu.eg" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author

Affiliation:	(1) Department of Chemistry, Faculty of Science, Mansoura University, 35516 Mansoura, Egypt

Abstract:	Summary. Group 2B transition metal complexes of bis[N-(2,6-diisopropylphenyl)imino]acenaphthene (o,o-iPr₂C₆H₃-BIAN), namely, [Hg(o,o-iPr₂C₆H₃-BIAN)Cl₂] (1), [Zn(o,o-iPr₂C₆H₃-BIAN)₂](ClO₄)₂ (2), and [Cd(o,o-iPr₂C₆H₃-BIAN)₂](ClO₄)₂ (3) have been synthesized and characterized. In complexes 2 and 3, IR, NMR, and conductivity measurements confirm the coordination of two (o,o-iPr₂C₆H₃-BIAN) ligands to the metal center with two discrete perchlorate anions. X-Ray crystal structure of 1 indicates a distorted tetrahedral geometry with two nitrogen atoms from (o,o-iPr₂C₆H₃-BIAN) ligand and two chloride atoms coordinating to the Hg(II) center.

Keywords:	. N-Ligands X-Ray structure determination Group 2B transition metal complexes.
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