Ring-chain isomerism of 1,3,3-trimethyl-2-formylmethylene-indoline (fischer aldehyde) oxime and associated reactions |
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| Authors: | A. A. Tolmachev L. N. Babichenko I. V. Komarov S. V. Sereda A. K. Sheinkman |
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| Affiliation: | (1) Institute of Organic Chemistry, Ukrainian Academy of Sciences, Kiev;(2) Dnepropetrovsk Engineering and Construction Institute, Dnepropetrovsk |
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| Abstract: | The compound 1,3,3-trimethyl-2-formylmethyleneindoline oxime is synthesized for the first time. Using the polynuclear resonance method it is shown that the oxime exists as two isomers, one of which has a cyclic structure. A number of reactions are carried out involving the carbocyclic and oxime parts of the molecule.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 183–189, February, 1992. |
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