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Differential pulse anodic stripping voltammetric determination of Cd and Pb at a bismuth glassy carbon electrode modified with Nafion, poly(2,5-dimercapto-1,3,4-thiadiazole) and multiwalled carbon nanotubes |
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| Authors: | Xiuhui He Zhaohong Su Qingji Xie Chao Chen Yingchun Fu Li Chen Ying Liu Ming Ma Le Deng Dilan Qin Yueping Luo Shouzhuo Yao |
| Affiliation: | 1. College of Chemistry, Jilin University, Changchun, 130022, China 2. State Key Laboratory of Electroanalytical Chemistry, National Research Center of Electroanalytical and Spectroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China |
| Abstract: | A simple, cheap, and nonpolluting method was developed for the cloud point extraction of gold (Au) and palladium (Pd). It is based on the complexation reaction of Au and Pd with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP) and micelle mediated extraction of the complex using the non-ionic surfactant poly(ethylene glycol) mono-p-nonylphenyl ether (PONPE 7.5). Under the optimized experimental conditions, the enrichment factors are 16 and 17 for Au and Pd, respectively, for 15?mL of preconcentrated solution. The limits of detection are 3.8???g?L?1 and 1.8???g?L?1 for Au and Pd, respectively. The relative standard deviations are 1.4% for Au and 0.6% for Pd (n?=?11). The method was successfully applied to the determination of Au and Pd in certified reference materials and mine samples. CPE of gold(III) and palladium(II) |
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