Synthesis and X-ray crystal structure of a five-coordinate d8 complex: [Pt((Me2NN)(PMe2)(PPh2))2Cl][Cl] |
| |
| Authors: | C J Harlan T C Wright S G Bott J L Atwood |
| |
| Institution: | (1) Department of Chemistry, University of Texas at Arlington, 76019 Arlington, Texas;(2) Present address: Department of Chemistry, University of North Texas, 76230 Denton, Texas;(3) Department of Chemistry, University of Alabama, 35487 Tuscaloosa, Alabama |
| |
| Abstract: | C36H50Cl2N6P4Pt·2 MeCN,2, triclinic P¯1,a=11.720(2),b=12.153(2),c=16.196(3), =76.74(1),=84.90(1), =88.13(1),Z=2,R=0.051,Rw=0.051. Interaction of Me2NN(PMe2)(PPh2),1, with Pt(COD)Cl2, COD=1,5 cyclooctadiene, in THF yields the title compound,2, in quantitative yield. Compound2 was characterized spectroscopically as well as via an X-ray diffraction study. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
