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Synthesis and X-ray crystal structure of a five-coordinate d8 complex: [Pt((Me2NN)(PMe2)(PPh2))2Cl][Cl]
Authors:C J Harlan  T C Wright  S G Bott  J L Atwood
Institution:(1) Department of Chemistry, University of Texas at Arlington, 76019 Arlington, Texas;(2) Present address: Department of Chemistry, University of North Texas, 76230 Denton, Texas;(3) Department of Chemistry, University of Alabama, 35487 Tuscaloosa, Alabama
Abstract:C36H50Cl2N6P4Pt·2 MeCN,2, triclinic P¯1,a=11.720(2),b=12.153(2),c=16.196(3),agr=76.74(1),agr=84.90(1),gamma=88.13(1),Z=2,R=0.051,Rw=0.051. Interaction of Me2NN(PMe2)(PPh2),1, with Pt(COD)Cl2, COD=1,5 cyclooctadiene, in THF yields the title compound,2, in quantitative yield. Compound2 was characterized spectroscopically as well as via an X-ray diffraction study.
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