| Synthesis,Crystal Structure and Luminescent Properties of [Ag（bzdmpymt）]6·2MeOH （bzdmpymtH = 5-Benzyl-4,6-dimethylpyrimidine-2-thione） |
| |
| 引用本文： | 崔玉微,李红喜,唐晓艳,陈阳,郎建平. Synthesis,Crystal Structure and Luminescent Properties of [Ag（bzdmpymt）]6·2MeOH （bzdmpymtH = 5-Benzyl-4,6-dimethylpyrimidine-2-thione）[J]. 结构化学, 2009, 28(5): 631-635 |
| |
| 作者姓名： | 崔玉微 李红喜 唐晓艳 陈阳 郎建平 |
| |
| 作者单位： | Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, Suzhou 215123, China |
| |
| 基金项目： | 国家自然科学基金，江苏省教育厅自然科学基金，Soochow Scholar Program of Suzhou University |
| |
| 摘 要： | Reaction of AgAc with bzdmpymtH in MeOH resulted in the title compound [Ag（bzdmpymt）]6-2MeOH （1.2MeOH）, which was structurally characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis. 1.2MeOH belongs to the triclinic system, space group Pi, with a = 10.930（2）, b = 11.646（2）, c = 16.794（3）A, a = 103.97（3）, β = 97.07（3）, γ = 97.94（3）°, V = 2027.2（7） A3, Z = 1, μ = 1.629 mm^-1, Dc = 1.710 mg/m3, T = 193（2） K, CsoH86Ag6N12O2S6, Mr = 2087.25, F（000） = 1044, S = 1.034, R = 0.0355 and wR = 0.0709. In 1.2MeOH, six silver（I） atoms are held together by six bzdmpymt ligands through N and S atoms to form a water-wheel-shaped structure. Each Ag atom is coordinated by two S atoms from two bzdmpymt ligands and one N atom from the third bzdmpymt ligand, giving a trigonal planar coordination geometry. Interactions between the CH3 group of bzdmpymt ligand and one pyrimidyl nitrogen atom in an adjacent molecule afford a one-dimensional hydrogen-bonding chain running along the b axis. The luminescent property of 1.2MeOH was also investigated.
|
| 关 键 词： | 晶体结构 发光性能 硫原子 银原子 单晶X射线衍射分析 合成 苄基 标题化合物 |
Synthesis,Crystal Structure and Luminescent Properties of [Ag(bzdmpymt)]6·2MeOH (bzdmpymtH =5-Benzyl-4,6-dimethylpyrimidine-2-thione) |
| |
| CUI Yu-Wei,LI Hong-Xi,TANG Xiao-Yan,CHEN Yang,LANG Jian-Ping. Synthesis,Crystal Structure and Luminescent Properties of [Ag(bzdmpymt)]6·2MeOH (bzdmpymtH =5-Benzyl-4,6-dimethylpyrimidine-2-thione)[J]. Chinese Journal of Structural Chemistry, 2009, 28(5): 631-635 |
| |
| Authors: | CUI Yu-Wei LI Hong-Xi TANG Xiao-Yan CHEN Yang LANG Jian-Ping |
| |
| Affiliation: | Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, Suzhou 215123, China |
| |
| Abstract: | Reaction of AgAc with bzdmpymtH in MeOH resulted in the title compound group P1, with a = 10.930(2), b = 11.646(2), c = 16.794(3) A, α = 103.97(3), β = 97.07(3), γ = 97.94(3)°, V = 2027.2(7) A3, Z = 1, μ = 1.629 mm-1, Dc = 1.710 mg/m3, T = 193(2) K, C80H86Ag6N12O2S6, Mr = 2087.25, F(000) = 1044, S - 1.034, R = 0.0355 and wR = 0.0709. In form a water-wheel-shaped structure. Each Ag atom is coordinated by two S atoms from two bzdmpymt ligands and one N atom from the third bzdmpymt ligand, giving a trigonal planar coordination geometry. Interactions between the CH3 group of bzdmpymt ligand and one pyrimidyl nitrogen atom in an adjacent molecule afford a one-dimensional hydrogen-bonding chain running along the b axis. The luminescent property of 1·2MeOH was also investigated. |
| |
| Keywords: | synthesis crystal structure luminescent property |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
