Efficient and Z-selective cross-metathesis of conjugated enynes |
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Authors: | Hansen Eric C Lee Daesung |
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Institution: | Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA. |
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Abstract: | reaction: see text] The generation of a conjugated alkynyl alkylidene has been achieved using an allyl ether moiety as an intramolecular catalyst delivery vehicle. The reaction of this intermediate with alkenes and alkynes yields conjugated enynes with Z-selectivity. |
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