Hydroformylation reactions of the trans -Mo(CO)4( p -C5NH4SO3NA)2 complex in biphasic medium |
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| Authors: | Trino Suárez Bernardo Fontal Ghery Zambrano Marisela Reyes Fernando Bellandi Ricardo R. Contreras Juan C. Diaz Pedro Cancines Yuraima Fonseca Isolda Romero |
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| Affiliation: | (1) Facultad de Ciencias, Departamento de Química, Laboratorio de Organometálicos, Universidad de Los Andes, Mérida, 5101, Venezuela |
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| Abstract: | Trans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1-hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100°C, syngas total pressure = 600 psi, pH2/pCO = 1). Complex (1) showed good activity favoring the linear aldehyde. Likewise as other organic olefin substrates and with synthetic and real naphtha, good conversions to oxygenated products were obtained. |
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| Keywords: | Biphasic catalysis hydroformylation naphtha molybdenum complex |
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