Hosomi-Sakurai reactions of silacyclic allyl silanes |
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| Authors: | Sellars Jonathan D Steel Patrick G Turner Michael J |
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| Institution: | Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK DH1 3LE. |
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| Abstract: | Substituted silacyclohexenes, generated through silene-diene 4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres. |
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