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Synthesis of new indolyl crown ethers catalyzed with ferric hydrogensulfate
Authors:Hossein Eshghia  Mohammad Rahimizadeha  Zahra Bakhtiarpoora  Mehdi Pordelb a
Institution:Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, P. O. Box 91775-1436, Mashhad, Iran ; Department of Chemistry, Faculty of Sciences, Islamic Azad University, Mashhad Branch, Mashhad, Iran
Abstract:Efficient reaction of bis-indolyl podand with different aldehydes using Fe(HSO43 as catalyst to afford the corresponding new indolyl crown ethers is described.The structures of three distinct isomers have been optimized using HyperChem geometry optimizations.Also percentage of each isomer was obtained with 1H NMR spectroscopy.
Keywords:Ferric hydrogcnsulfate  Bis-indolyl podand  Indolyl crown ether  Fe(HSO43
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