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Kinetics of the DS-radical reactions with CINO and NO2
Authors:Frederick F. Fenter  James G. Anderson
Abstract:The rate constants for the reactions of the DS radical with NO2 (reaction 1) and ClNO (reaction 2) have been measured using the discharge-flow technique at 2 torr total pressure of helium. The DS radical was monitored by laser-induced fluorescence. The reactions were found to have the following bimolecular rate constants (95% confidence level, in units of cm3 molecule?1 s?1): equation image This expression for k1 is found to be in excellent agreement with one of several previous studies. The magnitude of k2 is examined within the framework of a well-established reactivity trend. © 1994 John Wiley & Sons, Inc.
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