Synthesis and reactions of 2-(alkylthio)-4,4-dimenthyl-1,3-thiazole-5(4H)-thiones |
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Authors: | Junxing Shi Anthony Linden Heinz Heimgartner |
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Abstract: | Six 2-(alkylthio)-substituted 4,4-dimethyl-1,3-thiazole-5(4H)-thiones were synthesized according to a new method. The reactions of these compounds with allyl- and benzyllithium reagents, 1,3-dipoles, and dimethyl acetylenedicarboxylate proceeded in a similar manner to 2-alkyl-substituted analogues, while methyllithium reacted in a different way yielding trithio-orthoester derivatives. |
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