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Unusual schmidt rearrangement of 7,7a,8,9,10,12-hexahydro benzo[h]pyrrolo[1,2-b]-isoquinoline-7,10-dione
Authors:Jean-Yves Mrour  Simone Piroëlle  Robert Faure
Institution:Jean-Yves Mérour,Simone Piroëlle,Robert Faure
Abstract:The reaction of 7,7a,8,9,10,12-hexahydrobenzoh]pyrrolo 1,2-b]isoquinoline-7,10-dione 2 with sodium azide in sulfuric acid afforded the unexpected cyano derivative 5 . The proposed structure for 5 is supported by 13C nmr, 1H nmr and HMBC spectra.
Keywords:
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