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Meso- to Macro-Porous Oxides as Semiconductor Gas Sensors
Authors:Yasuhiro Shimizu  Takeo Hyodo  Makoto Egashira
Affiliation:(1) Department of Chemical Engineering, Institute of Nirma University, Ahmedabad, Gujarat, 382481, India;(2) Department of Chemistry, Krantiguru Shyamji Krishna Verma Kachchh University, Mundra Road, Bhuj, Gujarat, 370 001, India;
Abstract:The present article reviews our latest studies directed to improving gas sensing properties of semiconductor metal oxides, SnO2 and TiO2, by controlling their porous structure in the range of nano- to micro-meter size. Thermally stable mesoporous oxide powders and submicron-size porous thick films were fabricated by a templating method employing supramolecular surfactants or polymethylmethacrylate microspheres and also by a sol–gel process in a polyethylene glycol matrix. Advantages of these methods in improving the sensing properties are overviewed and then remaining problems are discussed.
Keywords:nano-crystallite  ordered mesopore  tin dioxide  titanium dioxide  semiconductor gas sensors
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