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Complexes of Copper(II) Aryl Carboxylates with Picoline N-Oxides |
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| Authors: | N Kumar A K Gandotra A K Suri Rama Kant |
| Abstract: | Copper(II) aryl carboxylates on interaction with 2-picoline N-Oxide (2-picNO), 3-picoline N-Oxide (3-picNO) and 4-picoline N-Oxide (4-picNO) in acetone or ethyl acetate yield 1:1 adducts. These are regarded as binuclear bridged complexes of composition Cu2(RC6H4COO)2L2 where R is o-, m-, p-CH2; o-, m-Cl: o-NO2; m-, p-CH2O; and L is 2-, 3-, and 4-picNO ligand. With 4-picNO some 1:2 adducts have also been obtained. |
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