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Heat capacity of a white-eucalyptus biocarbon template for SiC/Si ecoceramics
Authors:L S Parfen’eva  B I Smirnov  I A Smirnova  D Wlosewicz  H Misiorek  A Jezowski  J Mucha  A R de Arellano-Lopez  J Martinez-Fernandez  F M Varela-Feria  A I Krivchikov
Institution:(1) Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia;(2) Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Wrocław, 50-950, Poland;(3) Universidad de Sevilla, Sevilla, 41080, Spain;(4) Institute for Low-Temperature Physics and Engineering, National Academy of Sciences of Ukraine, Kharkov, 31064, Ukraine
Abstract:The heat capacity C p of a biocarbon template based on white eucalyptus wood is measured at a constant pressure in the temperature range T = 3.5–300 K. The phonon mean free path l for a white-eucalyptus biocarbon template is calculated from the measured dependence C p (T) and data available in the literature on the phonon thermal conductivity and velocity of sound. It is established that, in the range 100–300 K, the phonon mean free path l is nearly constant and equal to ~13 Å. This value is close to the smallest size of graphite-like crystallites (~12 Å), which was derived earlier from x-ray diffraction data for a quasi-amorphous biocarbon template.
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