Kinetics of the decay of nitroxyl radicals during polymerization of a complex of acrylamide with bismuth nitrate |
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| Authors: | N P Piven' V S Savost'yanov S D Babenko A N Ponomarev |
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| Institution: | (1) Branch of the Institute of Energetic Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | Kinetics of the decay of nitroxyl radicals during spontaneous polymerization of complexes of acrylamide (AAm) with BiIII nitrate has been studied by ESR. From a comparison of the experimental and calculated kinetic curves, the initiation rate constant of polymerization has been determined. The approach proposed is suitable for determining the main kinetic characteristics of other polymerizable nonparamagnetic AAm complexes with metal nitrates.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1572–1575, September, 1994.This work was carried out with the financial support of the Russian Foundation for Basic Research (Project No93-03-4162). |
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| Keywords: | acrylamide bismuth nitrate complex polymerization ESR spectroscopy nitroxyl radicals |
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