Kinetic investigations on interaction of carbon monoxide with RuIICl2(PPh3)3 in mixed aqueous medium |
| |
| Authors: | Vivek K. Srivastava Ram S. Shukla Sharad D. Bhatt Raksh V. Jasra |
| |
| Affiliation: | (1) Silicates and Catalysis Division, Central Salt and Marine Chemicals Research Institute, Bhavnagar, 364002, India |
| |
| Abstract: | Kinetics, equilibrium and thermodynamics of interaction of CO with RuCl2(PPh3)3 (1) have been investigated in 1:1(v/v) water — 1,4-dioxan mixture in which 1 dissociates to RuCl2(PPh3)2 (1a), by losing a coordinated PPh3. The kinetics of complexation of (1a) with CO to form RuCl2(CO)(PPh3)2 (2) indicated first order dependence in [1a] and [CO]. The thermodynamic parameters for the formation of 2 were determined.This revised version was published online in December 2005 with corrections to the Cover Date. |
| |
| Keywords: | Kinetics carbon monoxide thermodynamics mixed aqueous medium |
| 本文献已被 SpringerLink 等数据库收录！ |
