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Reaction of fullerene with benzocyclobutene homologs
Authors:Tetsuya Tago  Toshiyuki Minowa  Yukihiro Okada  Jun Nishimura
Institution:

Department of Chemistry, Gunma University, Tenjincho, Kiryu 376, Japan

Abstract:Fullerene was easily converted to its derivatives by the treatment with benzocyclobutene homologs for 20 h at 140 °C. The spectroscopic analyses clearly indicate mono-4+2]-cycloadduct structures of its derivatives. Isolated yields of mono- and di-adducts were from 4.4 to 15.6% and from 8.1 to 5.3%, respectively.
Keywords:fullerene  Diels-Alder adducts  benzocyclobutene homologs  pyrene  
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