Chiral Sc-catalyzed asymmetric Michael reactions of thiols with enones in water |
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| Authors: | Ueno Masaharu Kitanosono Taku Sakai Masaru Kobayashi Shū |
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| Affiliation: | Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan. |
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| Abstract: | Asymmetric Michael reactions of thiols with enones were catalyzed by a Sc(OTf)(3)-chiral bipyridine complex at room temperature in water without using any organic solvents, to afford the desired sulfides in high yields with high enantioselectivities. |
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