| SYNTHESIS AND CROSSLINKING OF LIQUID ORGANOSILANE POLYMERS |
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| 引用本文： | 张兴华,Robert West. SYNTHESIS AND CROSSLINKING OF LIQUID ORGANOSILANE POLYMERS[J]. 高分子科学, 1986, 0(1): 24-34 |
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| 作者姓名： | 张兴华 Robert West |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing，Department of Chemistry，University of Wisconsin，Madison，W1 53706，U.S.A. |
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| 摘 要： | Liquid organosilane polmers have been synthesized by sodium coupling of diorganodichloro-silanes with diphenylmethylchlorosilane in toluene. These polysilanes can be formed into desiredshape by potting, casting or coating and crosslinked under ultraviolet irradiation in the presenceof multifunctional vi?ylsilanes. The molecular weight distributions, infra-red, ultraviolet andnuclear magnetic resonance spectra for the organosilane polymers have been described.
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| 收稿时间： | 1984-06-21 |
SYNTHESIS AND CROSSLINKING OF LIQUID ORGANOSILANE POLYMERS |
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| ZHANG Xinghua,Robert West. SYNTHESIS AND CROSSLINKING OF LIQUID ORGANOSILANE POLYMERS[J]. Chinese Journal of Polymer Science, 1986, 0(1): 24-34 |
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| Authors: | ZHANG Xinghua Robert West |
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| Affiliation: | Institute of Chemistry; Academia Sinica; Beijing Department of Chemistry; University of Wisconsin; Madison; W1 53706; U.S.A. |
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| Abstract: | Liquid organosilane polmers have been synthesized by sodium coupling of diorganodichloro-silanes with diphenylmethylchlorosilane in toluene. These polysilanes can be formed into desiredshape by potting, casting or coating and crosslinked under ultraviolet irradiation in the presenceof multifunctional vi?ylsilanes. The molecular weight distributions, infra-red, ultraviolet andnuclear magnetic resonance spectra for the organosilane polymers have been described. |
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